:::

Academic Performance

:::
Paper contents
Paper category碩士論文
Student ID No.9125603
Name林佩君
標題(中)整合零價金屬與電動力法復育有機污染土壤-以四氯乙烯為例-
標題(英)Integration of Zero-Valent Metal and Electrokinetics to Remediate Organic Contaminated Soil - exemplified by Perchloroethelene-
Adviser章日行
Graduation date2004-06
Attached file 
Reference linkhttp://ir.lib.cyut.edu.tw:8080/handle/310901800/1696
Abstract本研究之目的為探討零價金屬牆與電動力法整合技術去除土壤中含氯有機污染物之成效，並尋求此整合系統適當的操作參數。本整合系統的復育機制主要利用電動力技術的電滲透流傳送地層中含氯有機污染物，當污染物於傳送路徑中碰觸零價金屬，即可利用還原脫氯作用分解有毒污染物。實驗以四氯乙烯 (PCE) 為目標污染物並改變不同操作參數進行之，操作參數包括操作液種類、零價金屬牆位置、零價金屬種類、操作電壓梯度及電極板位置等，在為期10天處理時間中，針對系統中操作液之pH值、電導度、電流、孔隙水之pH值、PCE濃度、土壤重金屬含量、
Bibliography1. 劉振宇、陳增壽，「加油站地下油槽之管理」，環境工程會刊，第六卷，第二期，第57-64頁（1995）。
2. 2. 陳家洵，「地下水污染問題之討論」，應用倫理研究通訊，第3期（1997）。
3. 盧至人，「地下水的污染整治」，國立編譯館，台北（1998）。
4. 林財富、洪旭文，「透水性反應牆之設計介紹」，工業污染防治，第84期，第114-135頁 (2002)。
5. 田福助，「電化學-理論與應用」，高立圖書有限公司，第8-12頁 ，台北(1987)。
6. 田福助，「電化學理論與應用」，總經銷新科技書局，第1-196頁 ，台北(1993)。
7. 蔡秋華、郭錦洛，「台灣北部地區地下水氯化烴化合物污染調查」，地下水資源研討會論文集 (1988)。
8. 蔡文田，「含氯有機溶劑之毒性及新陳代謝機制」，工業污染防治，第11卷，第3期，第175-187頁 (1992)。
9. 袁菁、翁誌煌，「電動力復育技術之介紹」，環保訓練園地，行政院環保署環境保護人員訓練所，第58期（2002）。
10. 劉永章、葛煥彰，「電動力現象的基本理論」，化工，第45卷，第2期，77-83頁（1998）。
11. 洪肇嘉、吳惠銘、紀吉鴻、陳錕榮，“電動力復育鉻、鎘、鉛污染土壤研究”，第十三屆廢棄物處理技術研討會論文集，第312~318頁，高雄（1998）。
12. 袁菁、翁誌煌、陳威錦、江姿幸，「以複合界面活性劑操作流質提昇電動力技術處理四氯乙烯污染黏質土壤」，第十六屆廢棄物處理技術研討會論文集（2001）。
13. 翁誌煌、涂宏旭、袁菁，「串聯式電動力法復育受三氯乙烯污染黏質土壤之研究」，第七屆土壤污染整治研討會論文集（2001）。
14. 楊金鐘，林舜隆，「土壤污染電化學處理法-電動力整治技術」，經濟部工業局工業技術人才培育計畫講義-事業廢棄物處理技術講習訓練班（第二階段），高雄市，pp.315-349(1995).
15. 蔡欣怡，「三氯乙烯及四氯乙烯對人類肺癌細胞之毒性研究」，碩士論文，國立中央大學生命科學研究所（1999）。
16. 陳碩修，「氫氣對地下水中四氯乙烯厭氧生物分解之研究」，碩士論文，國立中興大學環境工程研究所，台中（2000）。
17. 程淑芬，「斗閘式現地地下水污染復育技術之探討-含氯有機化合物以零價金屬反應透水牆還原脫氯之研究」，博士論文，國立台灣大學環境工程研究所，台北（2000）。
18. 蔡燦華，「零價鐵技術袪除三氯乙烯之研究」，碩士論文，中央大學環境工程研究所，新竹（2000）。
19. 蔡政勳，「零價鐵反應牆處理三氯乙烯污染物之反應行為研究」，碩士論文，中央大學環境工程研究所，新竹（2000）。
20. 劉奇岳，「電動力-Fenton 法現地處理三氯乙烯及4-氯酚污染土壤之最佳操作條件探討」，碩士論文，國立中山大學環境工程研究所，高雄（1999）。
21. 廖盈智，「循環改良式電動力系統之電化學反應」，碩士論文，朝陽科技大學環境工程與管理研究所，台中（2002）。
22. 林正欣，「利用金屬鋅對氯酚電化學還原性脫氯之研究」，博士論文，國立台灣大學環境工程研究所，台北（1990）。
23. http：//www.epa.gov.tw/prog/database.asp，行政院環保署，毒理資料庫。
24. Acar Y. B., Gale R. J., G, and Hamed J., “Electrochemical Processing of Soils：Its Potential Use in Environmental Geotechnology and Significance of pH Gradients”, 2nd International Symposium on Environmental Geotechnology, Shanghai, China, May 14-17, Envo Publishing, Bethlehem, PA Vol.1, pp.25-38 (1989).
25. Abinash A., William J. F., Bruce O. G., John A. C., Joel Z. B. and P. G. Tratnyek,“Effect of Carbonate Species on the Kinetics of Dechlorination of 1,1,1-Trichloroethane by Zero - Valent Iron”, Environmental Science and Technology ,Vol.36, No.20,pp.4326-4333（2002）.
26. Acar Y. B., Alshawabkeh A. N., “Principles of Electrokinetic Remediation”, Environmental Science and Technology, Vol.27, No.13, pp.2638-2647 (1993).
27. Burris, D. R., T. J. Campbell, and V. S. Manoranjan,“Sorpion of Tricholroethylene and Tetracholroethylene in a Batch Reactive Metallic Iron-Water Systern”, Environmental Science and Technology ,Vol.29,No.11,pp.2850-2855（1995）.
28. Baraud, F., S. Tellier, and M. Astruc, “Temperature Effect on Ionic Transport During Soil Electrokinetic Treatment at Constant pH”, Journal of Hazardous Materials, Vol. 64, No.3, pp.263-281（1999）.
29. Bruell C. J., B. A. Segall and M. T.Walsh.,“Electroosmotic Removal of Gasoline Hydrocarbons and from Clay ”, Journal of Environmental Engineering, Vol.118, No. 1, pp. 68-83（1992）.
30. Cookson, J. T., “Bioremediation Engineering: Design and Application,” McGraw-Hill, Inc., New York (1995).
31. Clayton J. C., P.S.C. Rao, Michael D. A., “Degradation of perchloroethylene in Cosolvent Solutions by Zero-Valent Iron”, Journal of Hazardous Materials, B96, pp.65-78（2003）.
32. Casagrand L., “ The Application of Electro-osmosis to Practical Problems in Foundations and Earthwork ”,Department of Scientific and Industrial Research, Building Research, London, England, Technical Paper, No.30 (1947).
33. Criddle C. S. and P. L. McCarty, “Electrolytic Model System for Reductive Dehalogenation in Aqueous Environments ”, Environmental Science and Technology ,Vol.25, No.5,pp.973-978（1991）.
34. Crow, D. R., “Principles and Applicatons of Electrochemistry, Blackie Academic and Professional”, pp.9-12, Glasgow (1994) .
35. DiStefano, T. D., J. M. Gossett, and S. H. Zinder. “Reductive Decglorination of High Concentrations of Teetrachloroethene to Ethene by an Anaerobic Enrichment Culture on the Absence of Methanohenesis”, Appl. Environ. Microbiol. Vol.57, pp.2287-2292（1991）.
36. Freedman, D. L. and J. M.Gossett, “Biological Reductive Dechlorination of Tetrachloroethylene and Trichloroethylene to Ethylene under Methanogenic Conditions”, Appl. Environ. Microbiol. Vol.55, pp.2144-2151（1989）.
37. Fountain , J . C .,“ Technology for Dense Nonaqueous Phase Liquid Source Zone Rernediation ”, Ground – Water Remediation Technologies Analysis Center , TE – 98 - 02（1998）.
38. Farrell J., N. Melitas, M. Kason, and T. Li, “Electrochemical and Column Investigation of Iron- Meliated Reductive Dechlorination of Trichloroethylene and Perchlotoethylene”, Environmental Science and Technology ,Vol.34, No.12, pp.2549-2556（2000）.
39. Gillham, R. W. and S. F.O’Hannesin, “ Enhanced Degradation of Halogenated Aliphatics by Zero-Valent Iron ”, Ground Water, Vol.32, No.6, pp.958-967（1994）.
40. Gavaskar , A. R. , N. Gupta , B. M. Sass , R. J. Janosy , and D. O ’ Sullivan , Permeable Barriers for Groundwater Remediation : Design , Construcion , and Monitoring , Battelle Press , Columbus , Ohio , pp.21-26 (1998).
41. Gotpagar, J., E. Grulke, T. Tsang, and D. Bhattacharyya, “Reductive Dehalogenation of Trichloroethylene Using Zero-Valent Iron”, Environmental Progress, Vol. 16, No. 2, pp. 137-143（1997）.
42. Grittini, C., Malcomson, M., Fernando, Q., Korte, N., “Rapid dechlorination of polychlorinated biphenyls on the surface of a Pd/Fe bimetallic system”, Environmental Science and Technology ,Vol.29,No.11,pp.2898-2900（1995）.
43. Hamada, T.and H. Thank, “Transfer of methyl Chlorofrom, Trichloroethylene And Tetrachlorcethlene to milk , Tissmes and Ekpired air following intrauminal or oral administration in lactating Goats and milk-fed kids.”Environmental pollution.,Vol.87,pp.313-318（1995）.
44. Hamed, J. T. and A. Bhadra, “Influence of Current Density and pH on Electrokinetics”, Journal of Hazardous Materials, Vol.55, No.3, pp. 279-294（1997）.
45. Johnson, T. L., M. M. Scherer, and P. G. Tratnyek,“Kinetics of Halogenated Organic Compound Degradation by Iron Metal”, Environmental Science and Technology ,Vol.30,No.8,pp.2634-2640（1996）.
46. James F., N. Melitas, and T. Li,“Investigation of the Long-Term Performance of Zero-Valent Iron for Reductive Dechlorination of Trichloroethylene”, Environmental Science and Technology ,Vol.34,No.3,pp.514-521（2000）.
47. Khan L. I., Pamukcu S., Kugelman I., “Electro-osmosis in Fine-grained Soil”, 2nd International Symposium on Environmental Geotechnology, Shanghai, China, May 14-17, Envo Publishing, Bethlehem, PA Vol.1, pp.39-47 (1989).
48. Li, T., and J. Farrell, “ Reductive Dechlorination of Trichloroethylene and Carbon Tetrachloride Using Iron and Palladized Iron Cathodes”, Environmental Science and Technology, Vol.34, No.1,pp.173-179（2000）.
49. Lee, H. H. and J. W. Yang, “A New Method to Contral Electrolyles pH by Circulytes Systerm in Electrokinetic Soil Remediation ”Journal of Hazardous Materials, Vol. 77, No.3, pp.227-240（2000）.
50. Matheson, L. J. and P. G. Tratnydk, “ Reductive Dehalogenation of Chlorinated Methanes by Iron Metal ”, Environmental Science and Technology, Vol.28, No.12, pp.2045-2053（1994）.
51. Muftikian R., Q. Fernanod and N. Korte, “A Methode for the Rapid Dechlorination of Low Molecular Weight Chlorinated Hydrocarbons in water”, Water Research, Vol. 29, No. 10, pp. 2434-2439（1995）.
52. Mckeague, J. A., and J. H. Day., “Dithionite and oxalate extractable Fe and Al as aids in differentiating various classes of soil ”, Can. Journal of Soil Science , Vol. 46, pp. 13-22（1966）.
53. Namkung, E. and Rittmann, B. E., “Estimating Volatile Organic Compound Emissions from Publicly Owned Treatment Works”, Journal of Water Pollution Control , Vol. 59,No.7, pp. 670-678（1987）.
54. Palmer , C . J . , and R . L . Johnson , “Physical Processes Controlling the Transport of Non-aqueous Phase Liquids in the Subsurface ” , Seminar Publication : Transport and Fate of Contarnants in the Subsurface , Chapter 3 , EPA / 625 / 4 – 89 / 019 , pp.23 - 28（1989）.
55. Paal Z., and P. G. Menon, “ Hydrogen Effects in Catalysis：Fundamentals and Practical Application”, M. Dekker, New York, pp.21-25 (1988 ).
56. Pael, J., and S. Shelton, “Permeable Barriers to Remove Benzene：Candidate Media Evaluation”, Journal of Environmental Engineering, ASCE, No.121, pp.411-415（1995）.
57. Peddie, C.C., S. Mavinic, and C. J. Jenkins, “Use of ORP for Monitoring and Control of Aerobic sludge digestion”, Journal of Environmental Engineering, Vol.116, No.3,pp.231-257（1990） .
58. Reed , B. E., Berg, M. T., Thompson, J. C., and Hatfield, J. H.,“Chemical Conditioning of Electrode Reservoirs During Electrokinetic Soil Flushing of Pb-Contaminated Silt Loam ”,Journal of Environmental Engineering , ASCE, Vol. 121, No. 11, pp. 805-815（1995）.
59. Rieger, P. H., “ELECTROCHEMISTRY”, Prentice-Hall, Inc.Englewood Cliffs, N. J.07632, 1987.
60. Rabbi, M. F. and B. Clark, “In Situ TCE Bioremediation Study Using Electrokinetic Cometabolite Injection”,Waste Management, Vol.20, pp.279-286（2000）.
61. Roh.Y,S. Y. Lee, M. P. Elless and H.-S. Moon, “Electro-enhanced Remediation of Trichloroethene-contaminated Groundwater Using Zero-valent Iron”, Journal of Environmental Science Health., Vol.A35, No.7, pp.1061-1076（2000）.
62. Sawyer, C. N., McCarty, P L., and Parkin, G. F., “Chemistry for Environmental Engineering, 4th edition”, McGraw-Hill, Singapore, pp.332-334（1994）.
63. Steven Y., K. Cantrell, B. Sass, and C. Steeffl,“ Multicomponent Reactive Transport in an In Situ Zero-Valent Iron Cell”, Environmental Science and Technology ,Vol.35, No.7, pp.1493-1503（2001）.
64. Scherer , M. M., S. Richter , R. L. Valentine, and P. J. J. Alvarez , “ Chemistry and Microbiology of Permeable Reactive Barriers for In Situ Groundwater Clean Up ” , Critical Reviews in Environmental Science and Technology , Vol .30, No. 3 , pp. 364 -411 ( 2000 ).
65. Schreier C. G. and M. Reinhard, “ Catalytic Hydrodehalogenation of Chlorinated Ethylenes Using Palladium and Hydrogen for the Treatment of Contaminated Water ”, Chemosphere, Vol.31, No.6, pp.3475-3487 (1995 ).
66. Tursman, J. F. and Cork, D. J., “Subsurface Contaminant Bioremediation Engineering,” Critical Reviews in Environmental Control, Vol. 22, No. 1/2, pp. 1-26 (1992).
67. U. S. EPA, “Permeable reactive barrier technologies for contaminant remediation ”,Office of Research and Development, Washington DC, EPA-600-R-98-125（1998）.
68. Vidic R. D., Pohland F. G., Technology Evalution Report TE-96-01：Treatment Walls, Groundwater Remediation Technology Analysis Center, Pittsburghm PA, (1996).
69. William A. A. and A. L. Roberts,“Pathways and Kinetics Chlorinated Ethylene and Chlorinated Acetylene Reaction with Fe（0） Particles”, Environmental Science and Technology ,Vol.34, No.9,pp.1794-1805（2000）.
70. Yang, G. C. C. and C.Y.Liu,“Remediation of TCE Contaminated Soil by In Situ EK-Fenton Process”, Journal of Hazardous Materials, Vol. 85, No.3, pp.317-331（2001）.
71. Yeo, S. D.,E. Tuncer, and A. Akgerman,“Adsorption of Volatile Organic Compounds on Soil Prediction of Desorption Breakthroughs”, Separation Science and Technology, Vol.32,No.23,pp.2497-251（1997） .

Gallery

Decorative imageDecorative imageDecorative imageDecorative imageDecorative imageDecorative image
cron web_use_log